全文获取类型
收费全文 | 14300篇 |
免费 | 2002篇 |
国内免费 | 1838篇 |
专业分类
化学 | 4039篇 |
晶体学 | 54篇 |
力学 | 789篇 |
综合类 | 303篇 |
数学 | 9358篇 |
物理学 | 3597篇 |
出版年
2024年 | 15篇 |
2023年 | 167篇 |
2022年 | 201篇 |
2021年 | 319篇 |
2020年 | 433篇 |
2019年 | 420篇 |
2018年 | 365篇 |
2017年 | 430篇 |
2016年 | 526篇 |
2015年 | 447篇 |
2014年 | 765篇 |
2013年 | 1055篇 |
2012年 | 710篇 |
2011年 | 913篇 |
2010年 | 802篇 |
2009年 | 1010篇 |
2008年 | 1087篇 |
2007年 | 1110篇 |
2006年 | 920篇 |
2005年 | 849篇 |
2004年 | 699篇 |
2003年 | 717篇 |
2002年 | 603篇 |
2001年 | 456篇 |
2000年 | 492篇 |
1999年 | 456篇 |
1998年 | 425篇 |
1997年 | 353篇 |
1996年 | 273篇 |
1995年 | 166篇 |
1994年 | 176篇 |
1993年 | 113篇 |
1992年 | 100篇 |
1991年 | 76篇 |
1990年 | 60篇 |
1989年 | 39篇 |
1988年 | 48篇 |
1987年 | 28篇 |
1986年 | 32篇 |
1985年 | 42篇 |
1984年 | 39篇 |
1983年 | 15篇 |
1982年 | 39篇 |
1981年 | 20篇 |
1980年 | 26篇 |
1979年 | 28篇 |
1978年 | 14篇 |
1977年 | 14篇 |
1976年 | 11篇 |
1974年 | 8篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
41.
设(χ,d,μ)是一个同时满足上双倍条件和几何双倍条件的非齐度量测度空间,对于引进的一类非齐度量测度空间上的Morrey-Herz空间,利用非齐度量测度空间的特征,证明了广义分数次积分算子及其交换子在非齐度量测度空间上MorreyHerz空间的有界性. 相似文献
42.
Jiang Tian Liu Hannes Hase Sarah Taylor Ingo Salzmann Pat Forgione 《Angewandte Chemie (International ed. in English)》2020,59(18):7146-7153
A library of symmetrical linear oligothiophene was prepared employing decarboxylative cross‐coupling reaction as the key transformation. Thiophene potassium carboxylate salts were used as cross‐coupling partners without the need of co‐catalyst, base, or additives. This method demonstrates complete chemoselectivity and is a comprehensive greener approach compared to the existing methods. The modularity of this approach is demonstrated with the preparation of discreet oligothiophenes with up to 10 thiophene repeat units. Symmetrical oligothiophenes are prototypical organic semiconductors where their molecular electrical doping as a function of the chain length can be assessed spectroscopically. An oligothiophene critical length for integer charge transfer was observed to be 10 thiophene units, highlighting the potential use of discrete oligothiophenes as doped conduction or injection layers in organic electronics applications. 相似文献
43.
The fundamental equation of the thermodynamic system gives the relation between the internal energy, entropy and volume of two adjacent equilibrium states. Taking a higher-dimensional charged Gauss–Bonnet black hole in de Sitter space as a thermodynamic system, the state parameters have to meet the fundamental equation of thermodynamics. We introduce the effective thermodynamic quantities to describe the black hole in de Sitter space. Considering that in the lukewarm case the temperature of the black hole horizon is equal to that of the cosmological horizon, we conjecture that the effective temperature has the same value. In this way, we can obtain the entropy formula of spacetime by solving the differential equation. We find that the total entropy contains an extra term besides the sum of the entropies of the two horizons. The corrected term of the entropy is a function of the ratio of the black hole horizon radius to the cosmological horizon radius, and is independent of the charge of the spacetime. 相似文献
44.
《Physics letters. A》2020,384(31):126794
An analytical approach for the electronic stopping force for non-relativistic energies that has no adjustable parameters has been developed. The approach combines the Bohr model for the close collisions and the Firsov model for the distant collisions. In order to combine the two models, a probabilistic model was introduced. We have applied our model to 16O in 12C, 16O in 27Al, 84 Kr in 27Al, 5Li in 12C, 12C in 12C, and 132Xe in 12C systems and compared with SRIM/MSTAR software, the original Bohr model, the Firsov model and available experimental data. We have found that the calculated electronic stopping force values are in agreement with the general qualitative behaviour of the electronic stopping force as a function of particle velocity reported in the literature. The proposed analytical formula is expected to be valid for other projectile-target combinations but more experimental data are needed to verify this assumption. 相似文献
45.
The Fefferman space of a contact Riemannian manifold carries a Lorentzian spin structure canonically. On the Lorentzian spin manifold, we investigate the Dirac operator and the twistor operator closely. In particular, we show that, if the contact Riemannian manifold is integrable, then there exist non-zero global solutions of the twistor equation. 相似文献
46.
We explore the non-commutative (NC) effects on the energy spectrum of a two-dimensional hydrogen atom. We consider a confined particle in a central potential and study the modified energy states of the hydrogen atom in both coordinates and momenta of non-commutativity spaces. By considering the Rashba interaction, we observe that the degeneracy of states can also be removed due to the spin of the particle in the presence of NC space. We obtain the upper bounds for both coordinates and momenta versions of NC parameters by the splitting of the energy levels in the hydrogen atom with Rashba coupling. Finally, we find a connection between the NC parameters and Lorentz violation parameters with the Rashba interaction. 相似文献
47.
Dr. Aleksandra Markovic Luca Gerhards Dr. Pia Sander Dr. Carsten Dosche Prof. Dr. Thorsten Klüner Prof. Dr. Rüdiger Beckhaus Prof. Gunther Wittstock 《Chemphyschem》2020,21(22):2506-2514
Multinuclear transition metal complexes bridged by ligands with extended π-electronic systems show a variety of complex electronic transitions and electron transfer reactions. While a systematic understanding of the photochemistry and electrochemistry has been attained for binuclear complexes, much less is known about trinuclear complexes such as hexaphenyl-5,6,11,12,17,18-hexaazatrinaphthylene-tristitanocene [(Cp2Ti)3HATN(Ph)6]. The voltammogram of [(Cp2Ti)3HATN(Ph)6] shows six oxidation and three reduction waves. Solution spectra of [(Cp2Ti)3HATN(Ph)6] and of the electrochemically formed oxidation products show electronic transitions in the UV, visible and the NIR ranges. Density functional theory (DFT) and linear response time-dependent DFT show that the three formally titanium(II) centers transfer an electron to the HATN ligand in the ground state. The optically excited transitions occur exclusively between ligand-centered orbitals. The charged titanium centers only provide an electrostatic frame to the extended π-electronic system. Complete active self-consistent field (CASSCF) calculation on a structurally simplified model compound, which considers the multi-reference character imposed by the three titanium centers, can provide an interpretation of the experimentally observed temperature-dependent magnetic behavior of the different redox states of the title compound in full consistency with the interpretation of the electronic spectra. 相似文献
48.
针对柱状装药的周向预制破片战斗部,结合无量纲分析方法和爆炸驱动理论,确定了影响破片和冲击波相遇位置的关键参数,给出了由缩比战斗部推广预测原型战斗部爆炸产生的破片冲击波作用时序的方法。采用ANSYS/LS-DYNA有限元软件进行数值模拟,对比验证了理论分析和数值试验结果,分析了战斗部缩比比例对冲击波和破片作用时序的影响。结果表明:缩比模型与原型战斗部爆炸产生的破片和冲击波的相遇位置之比和相遇时间之比主要取决于两模型的质量比,在不考虑破片速度衰减时,两模型中载荷相遇位置之比和相遇时间之比等于其质量比的0.33次方。受破片速度衰减影响,该方法仅适用于质量缩比不小于0.2的模型。 相似文献
49.
50.
The eigenvalues of a differential operator on a Hilbert-Pόlya space are determined. It is shown that these eigenvalues are exactly the nontrivial zeros of the Riemann $\zeta$-function. Moreover, their corresponding multiplicities are the same. 相似文献